Use pandas.concat and reindex new dataframe:
import pandas as pd
df = pd.DataFrame({'name': ['jon','sam','jane','bob'],
'age': [30,25,18,26],
'sex':['male','male','female','male']})
# new line
line = pd.DataFrame({'name': 'dean', 'age': 45, 'sex': 'male'}, index=[0])
# concatenate two dataframe
df2 = pd.concat([line,df.ix[:]]).reset_index(drop=True)
print (df2)
Output:
age name sex
0 45 dean male
1 30 jon male
2 25 sam male
3 18 jane female
4 26 bob male