I have various extension methods in my MiscUtil project (full source is available there - I'm not going to repeat it here). My favourites, some of which involve other classes (such as ranges):
Date and time stuff - mostly for unit tests. Not sure I'd use them in production :)
var birthday = 19.June(1976);
var workingDay = 7.Hours() + 30.Minutes();
Ranges and stepping - massive thanks to Marc Gravell for his operator stuff to make this possible:
var evenNaturals = 2.To(int.MaxValue).Step(2);
var daysSinceBirth = birthday.To(DateTime.Today).Step(1.Days());
Comparisons:
var myComparer = ProjectionComparer.Create(Person p => p.Name);
var next = myComparer.ThenBy(p => p.Age);
var reversed = myComparer.Reverse();
Argument checking:
x.ThrowIfNull("x");
LINQ to XML applied to anonymous types (or other types with appropriate properties):
// Jon32
new { Name="Jon", Age=32}.ToXElements();
// Name="Jon" Age="32" (as XAttributes, obviously)
new { Name="Jon", Age=32}.ToXAttributes()
Push LINQ - would take too long to explain here, but search for it.