I have following 2 data frames:
df_a =
mukey DI PI
0 100000 35 14
1 1000005 44 14
2 1000006 44 14
3 1000007 43 13
4 1000008 43 13
df
The .join() function is using the index of the passed as argument dataset, so you should use set_index or use .merge function instead.
Please find the two examples that should work in your case:
join_df = LS_sgo.join(MSU_pi.set_index('mukey'), on='mukey', how='left')
or
join_df = df_a.merge(df_b, on='mukey', how='left')