Not really hidden, but as a non-ML person this escaped me for quite a while:
Pattern matching can decompose arbitrarily deep into data structures.
Here's a [incredibly arbitrary] nested tuple example; this works on lists or unions or any combinations of nested values:
let listEven =
"Manipulating strings can be intriguing using F#".Split ' '
|> List.ofArray
|> List.map (fun x -> (x.Length % 2 = 0, x.Contains "i"), x)
|> List.choose
( function (true, true), s -> Some s
| _, "F#" -> Some "language"
| _ -> None )