One of the stated reasons for knowing assembler is that, on occasion, it can be employed to write code that will be more performant than writing that code in a higher-level
More often than you think, C needs to do things that seem to be unneccessary from an Assembly coder's point of view just because the C standards say so.
Integer promotion, for example. If you want to shift a char variable in C, one would usually expect that the code would do in fact just that, a single bit shift.
The standards, however, enforce the compiler to do a sign extend to int before the shift and truncate the result to char afterwards which might complicate code depending on the target processor's architecture.