I need an algorithm that can do a one-to-one mapping (ie. no collision) of a 32-bit signed integer onto another 32-bit signed integer.
My real concern is enough entr
Use any 32-bit block cipher! By definition, a block cipher maps every possible input value in its range to a unique output value, in a reversible fashion, and by design, it's difficult to determine what any given value will map to without the key. Simply pick a key, keep it secret if security or obscurity is important, and use the cipher as your transformation.
For an extension of this idea to non-power-of-2 ranges, see my post on Secure Permutations with Block Ciphers.
Addressing your specific concerns: