There are multiple sections in the manpages. Two of them are:
2 Unix and C system calls 3 C Library routines for C programs
For example there i
The calls described in section 2 of the manual are all relatively thin wrappers around actual calls to system services that trap to the kernel. The C standard library routines described in section 3 of the manual are client-side library functions that may or may not actually use system calls.
This posting has a description of system calls and trapping to the kernel (in a slightly different context) and explains the underlying mechanism behind system calls with some references.