A macro is just a straight text substitution. After preprocessing, your code looks like:
int main()
{
int a, b=3;
a = b+5*b+5;
printf("%d\n",a);
return 0;
}
Multiplication has a higher operator precedence than addition, so it's done before the two additions when calculating the value for a. Adding parentheses to your macro definition fixes the problem by making it:
int main()
{
int a, b=3;
a = (b+5)*(b+5);
printf("%d\n",a);
return 0;
}
The parenthesized operations are evaluated before the multiplication, so the additions happen first now, and you get the a = 64 result that you expect.