I have been creating an Email program using Tkinter, in Python 3.3. On various sites I have been seeing that the Frame widget can get a different background using <
You use ttk.Frame, bg option does not work for it. You should create style and apply it to the frame.
from tkinter import *
from tkinter.ttk import *
root = Tk()
s = Style()
s.configure('My.TFrame', background='red')
mail1 = Frame(root, style='My.TFrame')
mail1.place(height=70, width=400, x=83, y=109)
mail1.config()
root.mainloop()