Json value may consist of a string value. eg.:
postgres=# SELECT to_json(\'Some \"text\"\'::TEXT); to_json ----------------- \"Some \\\"text\\\"\"
In 9.4.4 using the #>> operator works for me:
select to_json('test'::text) #>> '{}';
To use with a table column:
select jsoncol #>> '{}' from mytable;