Awk is a funny way for this case:
~$ cat test.txt
tom
tom@gmail.com
jack
jack@gmail.com
marry
marry@gmail.com
gogo
gogo@gmail.com
~$ cat test.txt | awk 'BEGIN{c=1}{a=c;if(a==2){print b" "$0;c=1} if(a==1){b=$0;c=2}}'
tom tom@gmail.com
jack jack@gmail.com
marry marry@gmail.com
gogo gogo@gmail.com