Why I\'m getting this PHP error?
Fatal error: Class \'PHPUnit_Framework_TestCase\' not found in ...
It may well be that you're running WordPress core tests, and have recently upgraded your PhpUnit to version 6. If that's the case, then the recent change to namespacing in PhpUnit will have broken your code.
Fortunately, there's a patch to the core tests at https://core.trac.wordpress.org/changeset/40547 which will work around the problem. It also includes changes to travis.yml, which you may not have in your setup; if that's the case then you'll need to edit the .diff file to ignore the Travis patch.
Edit the patch file to remove the Travis part of the patch if you don't need that. Delete from the top of the file to just above this line:
Index: /branches/4.7/tests/phpunit/includes/bootstrap.php
Save the diff in the directory above your /includes/ directory - in my case this was the Wordpress directory itself
Use the Unix patch tool to patch the files. You'll also need to strip the first few slashes to move from an absolute to a relative directory structure. As you can see from point 3 above, there are five slashes before the include directory, which a -p5 flag will get rid of for you.
$ cd [WORDPRESS DIRECTORY]
$ patch -p5 < changeset_40547.diff
After I did this my tests ran correctly again.