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I've implemented both vector and deque multiple times. deque is hugely more complicated from an implementation point of view. This complication translates to more code and more complex code. So you'll typically see a code size hit when you choose deque over vector. You may also experience a small speed hit if your code uses only the things the vector excels at (i.e. push_back).
If you need a double ended queue, deque is the clear winner. But if you're doing most of your inserts and erases at the back, vector is going to be the clear winner. When you're unsure, declare your container with a typedef (so it is easy to switch back and forth), and measure.