I just discovered I can no longer gem push … any more and some digging led me to a need to update my RVM SSL certs.
I ran rvm osx-ssl-certs status
Your questions mentions three paths /opt/local, /usr/local and /etc/openssl they belong to Macports, Homebrew and SM Framework respectively.
As the last one is used to build static rubies it is harmeless and not related to the problem. The other two suggest that you have switched from macports to homebrew between installing the rubies.
You need to reinstall ruby-2.0.0-p195 which is referring still the old paths from macports, you can do it with:
rvm reinstall ruby-2.0.0-p195
You can get more details about the rubies and openssl paths they use running:
rvm --debug osx-ssl-certs update all