From what I understand about a left outer join, the resulting table should never have more rows than the left table...Please let me know if this is wrong...
My left
You can expect this to increase if keys match more than one row in the other DataFrame:
In [11]: df = pd.DataFrame([[1, 3], [2, 4]], columns=['A', 'B'])
In [12]: df2 = pd.DataFrame([[1, 5], [1, 6]], columns=['A', 'C'])
In [13]: df.merge(df2, how='left') # merges on columns A
Out[13]:
A B C
0 1 3 5
1 1 3 6
2 2 4 NaN
To avoid this behaviour drop the duplicates in df2:
In [21]: df2.drop_duplicates(subset=['A']) # you can use take_last=True
Out[21]:
A C
0 1 5
In [22]: df.merge(df2.drop_duplicates(subset=['A']), how='left')
Out[22]:
A B C
0 1 3 5
1 2 4 NaN