Here's the source: http://svn.python.org/view/python/trunk/Python/bltinmodule.c?revision=81029&view=markup
In the builtin_sum function we have this bit of code:
/* reject string values for 'start' parameter */
if (PyObject_TypeCheck(result, &PyBaseString_Type)) {
PyErr_SetString(PyExc_TypeError,
"sum() can't sum strings [use ''.join(seq) instead]");
Py_DECREF(iter);
return NULL;
}
Py_INCREF(result);
}
So.. that's your answer.
It's explicitly checked in the code and rejected.