I would like to create a .txt file and write to it, and if the file already exists I just want to append some more lines:
string path = @\"E:\\AppServ\\Examp
string path = @"E:\AppServ\Example.txt";
File.AppendAllLines(path, new [] { "The very first line!" });
See also File.AppendAllText(). AppendAllLines will add a newline to each line without having to put it there yourself.
Both methods will create the file if it doesn't exist so you don't have to.