There are a lot of good answers here but I noticed something was missing. Most answers seem to be implying that the reason why people use Big O over Big Theta is a difficulty issue, and in some cases this may be true. Often a proof that leads to a Big Theta result is far more involved than one that results in Big O. This usually holds true, but I do not believe this has a large relation to using one analysis over the other.
When talking about complexity we can say many things. Big O time complexity is just telling us what an algorithm is guarantied to run within, an upper bound. Big Omega is far less often discussed and tells us the minimum time an algorithm is guarantied to run, a lower bound. Now Big Theta tells us that both of these numbers are in fact the same for a given analysis. This tells us that the application has a very strict run time, that can only deviate by a value asymptoticly less than our complexity. Many algorithms simply do not have upper and lower bounds that happen to be asymptoticly equivalent.
So as to your question using Big O in place of Big Theta would technically always be valid, while using Big Theta in place of Big O would only be valid when Big O and Big Omega happened to be equal. For instance insertion sort has a time complexity of Big О at n^2, but its best case scenario puts its Big Omega at n. In this case it would not be correct to say that its time complexity is Big Theta of n or n^2 as they are two different bounds and should be treated as such.
