Substring and Join methods are usable for this statement.
string no = "12345";
string [] numberArray = new string[no.Length];
int counter = 0;
for (int i = 0; i < no.Length; i++)
{
numberArray[i] = no.Substring(counter, 1); // 1 is split length
counter++;
}
Console.WriteLine(string.Join(" ", numberArray)); //output >>> 0 1 2 3 4 5