Why doesn't GCC optimize structs?

Question

Systems demand that certain primitives be aligned to certain points within the memory (ints to bytes that are multiples of 4, shorts to bytes that are multiples of 2, etc.).

Answer 1

GCC is smarter than most of us in producing machine code from our source code; however, I shiver if it was smarter than us in re-arranging our structs, since it's data that e.g. can be written to a file. A struct that starts with 4 chars and then has a 4 byte integer would be useless if read on another system where GCC decided that it should re-arrange the struct members.