Why doesn't GCC optimize structs?

Question

Systems demand that certain primitives be aligned to certain points within the memory (ints to bytes that are multiples of 4, shorts to bytes that are multiples of 2, etc.).

Answer 1

Structs are frequently used as representations of the packing order of binary file formats and network protocols. This would break if that were done. In addition, different compilers would optimize things differently and linking code together from both would be impossible. This simply isn't feasible.