Can I pair two devices over Bluetooth without a need to confirm this in user interface, accept to pair this devices. Can I exchange some extra data over, for example NFC, an
If you are asking if you can pair two devices without the user EVER approving the pairing, no it cannot be done, it is a security feature. If you are paired over Bluetooth there is no need to exchange data over NFC, just exchange data over the Bluetooth link.
I don't think you can circumvent Bluetooth security by passing an authentication packet over NFC, but I could be wrong.