I am trying to add C:\\xampp\\php to my system PATH environment variable in Windows.
I have already added it using the Environment Varia
You don't need any set or setx command. Simply open the terminal and type:
PATH
This shows the current value of PATH variable. Now you want to add directory to it? Simply type:
PATH %PATH%;C:\xampp\php
If for any reason you want to clear the PATH variable (no paths at all or delete all paths in it), type:
PATH ;
Update
Like Danial Wilson noted in comment below, it sets the path only in the current session. To set the path permanently, use setx but be aware, although that sets the path permanently, but not in the current session, so you have to start a new command line to see the changes. More information is here.
To check if an environmental variable exist or see its value, use the ECHO command:
echo %YOUR_ENV_VARIABLE%