I have carefully read the CARET documentation at: http://caret.r-forge.r-project.org/training.html, the vignettes, and everything is quite clear (the examples on the website hel
If you are not sure what role method plays if you use index, why not to apply all the methods and compare results. It is a blind method of comparaison, but it can give you some intuitions.
  methods <- c('boot', 'boot632', 'cv', 
               'repeatedcv', 'LOOCV', 'LGOCV')
I create my index:
  n <- 100
  tmp <- createDataPartition(logBBB,p = .8, times = n)
I apply trainControl for my list of method, and I remove index from result since it is common to all my methods.
ll <- lapply(methods,function(x)
         trControl = trainControl(method = x, index = tmp))
ll <- sapply(ll,'[<-','index', NULL)
Hence my ll is :
                 [,1]      [,2]      [,3]      [,4]         [,5]      [,6]     
method            "boot"    "boot632" "cv"      "repeatedcv" "LOOCV"   "LGOCV"  
number            25        25        10        10           25        25       
repeats           25        25        1         1            25        25       
verboseIter       FALSE     FALSE     FALSE     FALSE        FALSE     FALSE    
returnData        TRUE      TRUE      TRUE      TRUE         TRUE      TRUE     
returnResamp      "final"   "final"   "final"   "final"      "final"   "final"  
savePredictions   FALSE     FALSE     FALSE     FALSE        FALSE     FALSE    
p                 0.75      0.75      0.75      0.75         0.75      0.75     
classProbs        FALSE     FALSE     FALSE     FALSE        FALSE     FALSE    
summaryFunction   ?         ?         ?         ?            ?         ?        
selectionFunction "best"    "best"    "best"    "best"       "best"    "best"   
preProcOptions    List,3    List,3    List,3    List,3       List,3    List,3   
custom            NULL      NULL      NULL      NULL         NULL      NULL     
timingSamps       0         0         0         0            0         0        
predictionBounds  Logical,2 Logical,2 Logical,2 Logical,2    Logical,2 Logical,2