I ask because I am sending a byte stream from a C process to Java. On the C side the 32 bit integer has the LSB is the first byte and MSB is the 4th byte.
So my ques
There's no way this could influence anything in Java, since there's no (direct non-API) way to map some bytes directly into an int in Java.
Every API that does this or something similar defines the behaviour pretty precisely, so you should look up the documentation of that API.