I would like to run a batch file I have that executes the following before a user logs on:
start \"VLC web Interface\" \"C:\\Program Files (x86)\\VideoLAN\\VLC\\
Create a local group policy object for a startup script.
Start up scripts run pre login.
To create what you are after:
The selected script will now run every time the PC starts. If the PC is part of a Windows Active Directory domain these settings will be overridden with AD Group Policy, in which case the admin of the network should be doing this for you.
Edit: It's been a few years since I wrote this, while this would work, it's probably simpler to go with Automate Everything's answer and use Task Scheduler to perform an "At Startup" action.