var a = new Array(4);
This defines a new array object with an explicit length of 4, but no elements.
var b = [undefined, undefined, undefined, undefined];
This defines a new array object with an implicit length of 4, with 4 elements, each with the value undefined.
From the docs:
callback is invoked only for indexes of the array which have assigned
values; it is not invoked for indexes which have been deleted or which
have never been assigned values.
For array a, there are no elements that have been assigned values, so it does nothing.
For array b, there are four elements that have been assigned values (yes, undefined is a value), so it maps all four elements to the number 14.