I am using the following to get a the lat-lng from a geocode..
$latitude = $output->results[0]->geometry->location->lat;
$longitude = $output->
I'd say you'd need to loop through results.address_components
. On each iteration check if the types array contains "postal_code". If it does, save that to a variable, and probably break out of the loop as well. Although it might be worth investigating to see if the postal_code is always in address_component[5], which would save you having to loop.