Right now I have to pull up Pending Changes window, right-click on the file and select Compare->With Latest Version... Is there a faster way to look at my modifications?
You can switch the double-click behaviour in the pending changes window to do a compare with latest by changing a registry setting:
Path: HKCU\Software\Microsoft\VisualStudio\\
TeamFoundation\SourceControl\Behavior
Value: DoubleClickOnChange (DWORD)
0 == view as the primary command (default)
1 == compare as primary command
You can find more information here:
A comment on that post also shows the entry to set if you want to use a shortcut key to do the comparison instead.