You are comparing your ASP.NET label dayToday against an enumeration element of DayOfWeek which of course fails
Probably you want to replace dayToday with day in your if statement, i.e. from
if ((dayToday == DayOfWeek.Saturday) && (dayToday == DayOfWeek.Sunday))
to
if ((day == DayOfWeek.Saturday) && (day == DayOfWeek.Sunday))
In addition, you probably also want to replace the logical 'and' (&&) with a logical 'or' (||) to finally
if ((day == DayOfWeek.Saturday) || (day == DayOfWeek.Sunday))